Electropolimerización de polipirrol usando electrodos de titanio
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oct 10, 2022
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Rosario Ramírez-Segundo
http://orcid.org/0009-0000-7584-2374
José Cuauhtémoc Palacios-González
http://orcid.org/0000-0003-1876-6226
Guillermo Jesús Cruz Cruz
http://orcid.org/0000-0003-4449-8982
María Guadalupe Olayo-González
http://orcid.org/0000-0002-7627-0563
Elena Colín-Orozco
http://orcid.org/0000-0002-4269-9601
Fernando Gabriel Flores-Nava
http://orcid.org/0000-0003-0894-6047
Maribel González-Torres
http://orcid.org/0000-0001-9239-0664
Lidia María Gómez-Jiménez
http://orcid.org/0000-0001-6920-2944
Ricardo Valdivia-Barrientos
http://orcid.org/0000-0001-5577-1441
http://orcid.org/0009-0000-7584-2374
José Cuauhtémoc Palacios-González
http://orcid.org/0000-0003-1876-6226
Guillermo Jesús Cruz Cruz
http://orcid.org/0000-0003-4449-8982
María Guadalupe Olayo-González
http://orcid.org/0000-0002-7627-0563
Elena Colín-Orozco
http://orcid.org/0000-0002-4269-9601
Fernando Gabriel Flores-Nava
http://orcid.org/0000-0003-0894-6047
Maribel González-Torres
http://orcid.org/0000-0001-9239-0664
Lidia María Gómez-Jiménez
http://orcid.org/0000-0001-6920-2944
Ricardo Valdivia-Barrientos
http://orcid.org/0000-0001-5577-1441
Resumen
En este trabajo se sintetizaron películas de polipirrol (PPy) por síntesis electroquímica usando un electrolito no convencional como yoduro de sodio (NaI) y electrodos de titanio (Ti). La película obtenida presentó una morfología rugosa con partículas sobre su superficie. El análisis elemental indico la presencia de C, N, O y I sobre la superficie de la película. Con la presencia de I, se demostró que el yodo se adhiere a la estructura del PPy. En el análisis estructural se observaron grupos conjugados de -C= representados como ≈C≈ y que no se encuentran en el pirrol, pero si en el polipirrol, lo que indica que las condiciones establecidas favorecieron el dopado del material.
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Como citar
RAMÍREZ-SEGUNDO, Rosario et al.
Electropolimerización de polipirrol usando electrodos de titanio.
Ideas en Ciencias de la Ingeniería, [S.l.], v. 1, n. 2, p. 42-52, oct. 2022.
ISSN 2992-7447.
Disponible en: <https://ideasencienciasingenieria.uaemex.mx/article/view/17327>. Fecha de acceso: 26 ago. 2026
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Esta obra está bajo licencia internacional Creative Commons Reconocimiento-NoComercial-SinObrasDerivadas 4.0.
Citas
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5. Jureviciute, I. & Bruckenstein, S. (2003). Electrochemical activity of chemically deposited polypyrrole films. Journal of Solid State Electrochemistry, 7(9), 554–560. https://doi.org/10.1007/s10008-003-0384-x
6. Lakard, B. (2020). Electrochemical Biosensors Based on Conducting Polymers: A Review. Applied Sciences. 10(18), 6614. https://doi.org/10.3390/app10186614
7. Lario-Femenía, J., Amigó Mata, A., Vicente-Escuder, A., Segovia-López, F. & Amigó, V. (2016). Desarrollo de las aleaciones de titanio y tratamientos superficiales para incrementar la vida útil de los implantes. Revista de Metalurgia, 52(4), e084-e096. https://doi.org/10.3989/revmetalm.084
8. Namsheer, K. & Chandra, S. R. (2021). Conducting polymers: a comprehensive review on re-cent advances in synthesis, properties and applications. RSC Advances. 11(10), 5659-5697. https://doi.org/10.1039/d0ra07800j
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10. Pang, A. L., Arsad, A. & Ahmadipour, M. (2020). Synthesis and factor affecting on the con-ductivity of polypyrrole: a short review. Polymers for Advanced Technologies, 32(4), 1428-1454. https://doi.org/10.1002/pat.5201
11. Patil, U. M., Kulkarni, S. B., Jamadade, V. S. & Lokhande, C. D. (2011). Chemically synthe-sized hydrous RuO2 thin films for supercapacitor application, Journal of Alloys and Com-pounds, 509(5), 1677–1682. https://doi.org/10.1016/j.jallcom.2010.09.133
12. Peña, W.F., Villard, J.F., Ramírez, A.E. & Nikolaevish, E. (2013). Synthesis and Voltametric Charac-terization of Plated Electrodes Doped with Cerium, Used for Degradation of 4-Chlorophenol. Revista Ciencia en Desarrollo, 4(2), 49-61.
13. Rowlands, A. S. & Cooper-White, J. J. (2008). Directing phenotype of vascular smooth muscle cells using electrically stimulated conducting polymer. Biomaterials, 29(34), 4510-4520. https://doi.org/10.1016/j.biomaterials.2008.07.052
14. Saugo, M., Flamini, D. O. & Saidman, S. B. (2018). Formación electroquímica de películas de polipirrol sobre Nitinol a partir de soluciones de ácido sulfuro-succínico. Revista Matéria, 23(2), 1517-7076. https://doi.org/10.1590/s1517-707620180002.0391
15. Stejskal, J., Sapurina, I. & Trchová, J. (2010). Polyaniline nanostructures and the role of aniline oligomers in their formation. Progress in Polymer Science, 35(12), 1420–1481. https://doi.org/10.1016/j.progpolymsci.2010.07.006
16. Thompson, B. C., Moulton, S. E., Richardson, R. T. & Wallace, G. G. (2011). Effect of the dopant ani-on in polypyrrole on nerve growth and release of a neurotrophic protein. Bio-materials, 32(15), 3822-3831. https://doi.org/10.1016/j.biomaterials.2011.01.053
17. Thorat, J. B., Mohite, S. V., Bagade, A. A. Shinde, T. J., Fulari, V. J. Raj-pure, K.Y. & Shine, N. S. (2018). Nanocrystalline Bi2Te3 thin films synthesized by electrodeposition method for photoelectrochemical application. Material Science in Semiconductor Processing, 79,119–126. https://doi.org/10.1016/j.mssp.2018.02.002
18. Wu J., Wu S. & Sun W. (2021). Electropolymerization and application of polyox-ometalate-doped polypyrrole film electrodes in dye-sensitized solar cells. Electrochemistry Communi-cations, 122, 106879. https://doi.org/10.1016/j.elecom.2020.106879
19. Zhang, J., Zhang, H., Wu, J. & Zhang, J. (2013). Techniques for PEM Fuel Cell Testing and Diagnosis en Zhang J., Zhang H., Wu J., Zhang J (Eds). Pem Fuel Cell Testing and Diagno-sis. (81–119). Elsevier.